River Plate knocked Unión out on penalties 4-3, after a 0-0 draw.

1. 0'
   ⚽Kick-off
   Copa Argentina 2025
   Coach: Leonardo Carol Madelón · Marcelo Daniel GallardoReferee: Carlos Andrés Gariano📍 Estadio Malvinas Argentinas
2. 1. Second half
   2. 65'
      ARG
      Substitution
      ▲Juan Quintero▼N. Fernandez
   3. 69'
      ARG
      Substitution
      ▲L. Gamba▼Cristian Tarragona
   4. 75'
      ARG
      Substitution
      ▲A. Solari▼Julián Palacios
   5. 75'
      ARG
      Substitution
      ▲S. Lencina▼Giuliano Galoppo
   6. 82'
      ARG
      Substitution
      ▲N. Palavecino▼F. Fragapane
   7. 82'
      ARG
      Substitution
      ▲A. Colazo▼M. Estigarribia
   8. 83'
      ARG
      Substitution
      ▲J. Portillo▼Enzo Pérez
   9. 83'
      ARG
      Substitution
      ▲Miguel Borja▼M. Salas
   10. 83'
       ARG
       Substitution
       ▲F. Colidio▼S. Driussi