Unión knocked Nueva Chicago out on penalties 4-2, after a 0-0 draw.

1. 0'
   ⚽Kick-off
   Copa Argentina 2016
   Coach: — · F. Argüello📍 Estadio Florencio Solá (Lomas de Zamora, Provincia de Buenos Aires)
2. 1. Second half
   2. 56'
      ARG
      Substitution
      ▲F. Soldano▼J. Tarquini
   3. 69'
      ARG
      Substitution
      ▲F. Pumpido▼M. Brito
   4. 72'
      ARG
      Substitution
      ▲G. Méndez▼B. Pitton
   5. 77'
      ARG
      Substitution
      ▲A. Vázquez▼C. Gómez
   6. 84'
      ARG
      Substitution
      ▲F. Britos▼S. Magallán