River Plate knocked Libertad Asuncion out on penalties 3-1, after a 1-1 draw. River Plate controlled the ball — 60% possession — but had nothing to show for it. River Plate played with ten from minute 52. Best on the pitch was F. Armani, rated 8.3.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 2025
   ARG 4-1-3-2·4-2-3-1 PAR
   Coach: Marcelo Daniel Gallardo · Pablo Horacio GuiñazúReferee: Andres Matonte, Uruguay📍 Estadio Monumental
2. 1. First half
   2. 18'
      PAR
      Yellow card
      Ivan Franco
   3. 20'
      ARG
      Yellow card
      Giuliano Galoppo
   4. 29'
      ARG
      GOOOAL!S. Driussi
   5. 43'
      PAR
      GOOOAL!R. RojasAssist: H. Fernandez
   6. 45+4'
      PAR
      Yellow card
      R. Rojas
3. 1. Second half
   2. 46'
      PAR
      Substitution
      ▲S. Boselli▼P. Diaz
   3. 52'
      ARG
      Yellow card
      Giuliano Galoppo
   4. 52'
      ARG
      Red card
      Giuliano Galoppo
   5. 54'
      PAR
      Substitution
      ▲M. Galarza▼Juan Quintero
   6. 61'
      ARG
      Substitution
      ▲H. Caballero▼A. Campuzano
   7. 61'
      ARG
      Substitution
      ▲M. Fernández▼H. Fernández
   8. 68'
      ARG
      Yellow card
      G. Montiel
   9. 68'
      PAR
      Substitution
      ▲Miguel Borja▼S. Driussi
   10. 70'
       ARG
       Yellow card
       N. Fernandez
   11. 77'
       ARG
       Substitution
       ▲Á. Cardozo Lucena▼Lucas Sanabria
   12. 77'
       ARG
       Substitution
       ▲R. Villalba▼Ivan Franco
   13. 79'
       PAR
       Substitution
       ▲K. Castano▼Enzo Pérez
   14. 79'
       PAR
       Substitution
       ▲Ian Subiabre▼F. Colidio
   15. 89'
       ARG
       Substitution
       ▲J. Recalde▼G. Aguilar
   16. 90+1'
       PAR
       Yellow card
       Á. Cardozo Lucena