Palmeiras beat U. Catolica 1-0. The winner had to work for it: 1 from 20 shots. Best on the pitch was S. Perez, rated 8.3.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 2021
   BRA 4-2-3-1·4-1-4-1 CHI
   Coach: Abel Ferreira · G. PoyetReferee: A. Herrera📍 Allianz Parque
2. 1. First half
   2. 30'
      CHI
      Yellow card
      A. Parot
   3. 33'
      BRA
      Yellow card
      Marcos Rocha
   4. 36'
      BRA
      GOOOAL!Marcos Rocha
   5. 40'
      BRA
      Yellow card
      Felipe Melo
3. 1. Second half
   2. 56'
      CHI
      Substitution
      ▲Francisco Silva▼I. Saavedra
   3. 56'
      CHI
      Substitution
      ▲T. Asta-Buruaga▼Raimundo Rebolledo
   4. 57'
      CHI
      Substitution
      ▲M. Nunez▼J. Leiva
   5. 68'
      BRA
      Substitution
      ▲Mayke▼Marcos Rocha
   6. 68'
      BRA
      Substitution
      ▲Breno Lopes▼Wesley
   7. 68'
      BRA
      Substitution
      ▲Dudu▼Raphael Veiga
   8. 75'
      BRA
      Yellow card
      Dudu
   9. 75'
      CHI
      Substitution
      ▲Clemente Montes▼A. Parot
   10. 75'
       CHI
       Substitution
       ▲D. Buonanotte▼Felipe Gutiérrez
   11. 80'
       BRA
       Yellow card
       Renan
   12. 83'
       BRA
       Substitution
       ▲B. Kuscevic▼Felipe Melo
   13. 86'
       BRA
       Yellow card
       Weverton
   14. 87'
       BRA
       Substitution
       ▲Gabriel Veron▼Deyverson
   15. 90+5'
       CHI
       Yellow card
       F. Zampedri