El Nacional beat Nacional Potosí 1-6. Nacional Potosí controlled the ball — 62% possession — but had nothing to show for it. J. Ordoñez scored 2 goals. Best on the pitch was J. Ordoñez, rated 8.7.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 2023
   BOL 3-4-1-2·4-4-2 ECU
   Coach: V. Andrada · E. AlmeidaReferee: Yender Herrera, Venezuela📍 Estadio Hernando Siles
2. 1. First half
   2. 5'
      ECU
      GOOOAL!J. OrdoñezAssist: J. Parrales
   3. 8'
      BOL
      Yellow card
      M. Prost
   4. 13'
      ECU
      GOOOAL!J. ChaláAssist: E. Mejía
   5. 16'
      ECU
      GOOOAL!R. Carrillo
   6. 23'
      BOL
      Substitution
      ▲T. Tobar▼M. Chiatti
   7. 26'
      ECU
      Yellow card
      J. Parrales
   8. 35'
      BOL
      Yellow card
      Marcos Andía
   9. 38'
      ECU
      GOOOAL!J. OrdoñezAssist: R. Carrillo
   10. 39'
       ECU
       VAR review
       R. Carrillo
   11. 43'
       ECU
       Yellow card
       R. Carrillo
   12. 45+1'
       BOL
       GOOOAL!M. ProstAssist: M. Núñez
   13. 45+4'
       ECU
       GOOOAL!M. SolísAssist: R. Carrillo
3. 1. Second half
   2. 46'
      BOL
      Substitution
      ▲S. Guerra▼D. Mancilla
   3. 46'
      BOL
      Substitution
      ▲Heber Leanos▼L. Pavia
   4. 59'
      ECU
      Substitution
      ▲G. Asprilla▼R. Carrillo
   5. 59'
      ECU
      Substitution
      ▲B. Palacios▼J. Ordoñez
   6. 59'
      ECU
      Substitution
      ▲D. Patiño▼E. Mejía
   7. 78'
      ECU
      Substitution
      ▲J. Orovio▼M. Julio
   8. 87'
      ECU
      Yellow card
      Bryan Nazareno
   9. 88'
      ECU
      Yellow card
      Andrés Micolta
   10. 88'
       ECU
       Substitution
       ▲M. Balda▼J. Valverde
   11. 89'
       ECU
       GOOOAL!G. AsprillaAssist: B. Palacios