Colo Colo beat Monagas SC 1-0. The winner had to work for it: 1 from 25 shots. Best on the pitch was O. Mosquera, rated 8.7.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 2023
   CHI 3-4-1-2·4-4-2 VEN
   Coach: G. Quinteros · J. FerreiraReferee: Anderson Daronco📍 Estadio Monumental David Arellano
2. 1. First half
   2. 45+4'
      VEN
      Yellow card
      O. González
   3. 45+6'
      CHI
      GOOOAL!Carlos PalaciosPenalty
3. 1. Second half
   2. 58'
      VEN
      Substitution
      ▲C. Rivas▼S. Herrera
   3. 58'
      VEN
      Substitution
      ▲Abdiel Arroyo▼Fernando Basante
   4. 63'
      VEN
      Yellow card
      A. Romero
   5. 68'
      CHI
      Substitution
      ▲Vicente Pizarro▼Carlos Palacios
   6. 72'
      VEN
      Yellow card
      Edson Castillo
   7. 74'
      VEN
      Substitution
      ▲L. Rodríguez▼Edson Castillo
   8. 83'
      CHI
      Substitution
      ▲L. Gil▼J. Rojas
   9. 87'
      VEN
      Substitution
      ▲Anthony Blondell▼H. Cummings
   10. 88'
       CHI
       Substitution
       ▲L. Benegas▼D. Pizarro
   11. 88'
       CHI
       Substitution
       ▲A. Oroz▼M. Bolados