Bolívar beat Barcelona SC 1-0. The winner had to work for it: 1 from 22 shots. Best on the pitch was R. Fernández, rated 8.2.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 2023
   BOL 3-4-3·4-2-3-1 ECU
   Coach: Beñat San José · F. BustosReferee: F. Gilabert📍 Estadio Hernando Siles
2. 1. First half
   2. 2'
      BOL
      Yellow card
      P. Rodríguez
   3. 45+2'
      BOL
      Yellow card
      N. Ferreyra
3. 1. Second half
   2. 46'
      ECU
      Substitution
      ▲Fidel Martínez▼J. Corozo
   3. 51'
      ECU
      Substitution
      ▲A. Rodríguez▼Adonis Preciado
   4. 51'
      ECU
      Substitution
      ▲J. Bauman▼C. Ortiz
   5. 56'
      ECU
      Substitution
      ▲G. Rendón▼Fidel Martínez
   6. 57'
      BOL
      Substitution
      ▲J. Uzeda▼Pablo Hervías
   7. 57'
      BOL
      Substitution
      ▲R. Vaca▼F. Saucedo
   8. 62'
      BOL
      Substitution
      ▲Jesús Sagredo▼J. Sagredo
   9. 63'
      BOL
      Substitution
      ▲Gabriel Poveda▼L. L. Chavez Cruz
   10. 67'
       ECU
       Yellow card
       B. Piñatares
   11. 67'
       ECU
       Yellow card
       Victor Mendoza
   12. 86'
       BOL
       Substitution
       ▲M. Villarroel▼D. Bejarano
   13. 88'
       ECU
       Yellow card
       F. Fydriszewski
   14. 90+5'
       ECU
       Yellow card
       L. Sosa
   15. 90+5'
       BOL
       GOOOAL!R. FernándezAssist: R. Vaca