Colo Colo beat Barcelona SC 2-3. Nivaldo scored 2 goals.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 1964
   Referee: Carlos Rivero📍 El Coloso de la Avenida de Las AméricasAttendance: 28,000
2. 1. First half
   2. 31'
      CHI
      GOOOAL!RFRoberto Frojuello
3. 1. Second half
   2. 55'
      CHI
      GOOOAL!LÁLuis Álvarez
   3. 59'
      CHI
      GOOOAL!FVFrancisco Valdés
   4. 64'
      ECU
      GOOOAL!NINivaldo
   5. 76'
      ECU
      GOOOAL!NINivaldo