Santos beat Penarol 5-4. Pelé scored 2 goals.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 1965
   Referee: Luis Ventre📍 PacaembúAttendance: 50,000
2. 1. First half
   2. 2'
      BRA
      GOOOAL!PEPelé
   3. 5'
      BRA
      GOOOAL!PEPepe
   4. 6'
      BRA
      GOOOAL!DODorval
   5. 18'
      URU
      GOOOAL!PRPedro Rocha
   6. 22'
      BRA
      GOOOAL!DODorval
   7. 24'
      URU
      GOOOAL!HSHéctor Silva
   8. 38'
      BRA
      GOOOAL!PEPelé
3. 1. Second half
   2. 74'
      URU
      GOOOAL!JSJose F. Sasia
   3. 86'
      URU
      GOOOAL!PRPedro Rocha