Deportivo Miranda beat U. Catolica 3-2. José Álvez scored 2 goals.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 1969
   Referee: Enrique Suárez📍 Olímpico de la UCVAttendance: 16,000
2. 1. First half
   2. 7'
      VEN
      GOOOAL!ADAdair
3. 1. Second half
   2. 49'
      VEN
      GOOOAL!JÁJosé Álvez
   3. 62'
      CHI
      GOOOAL!JSJuan Carlos Sarnari
   4. 64'
      VEN
      GOOOAL!JÁJosé Álvez
   5. 88'
      CHI
      GOOOAL!ADArmando Díaz