Bolívar beat Santos 4-3. Cristian G. Zermattén scored 3 goals.

1. 0'
   ⚽Kick-off
   CONMEBOL Libertadores 2005
   Referee: Carlos Torres📍 Libertador Simón BolívarAttendance: 30,000
2. 1. First half
   2. 1'
      BOL
      GOOOAL!CZCristian G. Zermattén
   3. 25'
      BRA
      GOOOAL!DEDeivid
3. 1. Second half
   2. 53'
      BOL
      GOOOAL!CZCristian G. Zermattén
   3. 56'
      BRA
      GOOOAL!DEDeivid
   4. 85'
      BOL
      GOOOAL!CZCristian G. Zermattén
   5. 87'
      BOL
      GOOOAL!DCDiego Cabrera
   6. 90'
      BRA
      GOOOAL!RORobinho